CHEMISTRY: Twisted Frameworks
نویسندگان
چکیده
منابع مشابه
Chemistry of Covalent Organic Frameworks.
Linking organic molecules by covalent bonds into extended solids typically generates amorphous, disordered materials. The ability to develop strategies for obtaining crystals of such solids is of interest because it opens the way for precise control of the geometry and functionality of the extended structure, and the stereochemical orientation of its constituents. Covalent organic frameworks (C...
متن کاملThe chemistry and applications of metal-organic frameworks.
Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among...
متن کاملExtending supramolecular fullerene-porphyrin chemistry to pillared metal-organic frameworks.
Porphyrins and fullerenes are spontaneously attracted to each other. This supramolecular recognition element can be exploited to produce ordered arrays of interleaved porphyrins and fullerenes. C(60) x H(2)TpyP x Pb(NO(3))(2) x 1.5TCE (H(2)TpyP = tetra-4-pyridylporphyrin; TCE = 1,1,2,2-tetrachloroethane) crystallizes in the tetragonal P4/n space group and the structure has been solved to high r...
متن کاملTwisted Aromatic Frameworks: Readily Exfoliable and Solution‐Processable Two‐Dimensional Conjugated Microporous Polymers
Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.
متن کاملTwisted bundles and twisted K-theory
Many papers have been devoted recently to twisted K-theory as originally defined in [15] and [29]. See for instance the references [2], [23] and the very accessible paper [30]. We offer here a more direct approach based on the notion of “twisted vector bundles”. This is not an entirely new idea, since we find it in [4], [6], [7], [8] and [9] for instance, under different names and from various ...
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ژورنال
عنوان ژورنال: Science
سال: 2001
ISSN: 0036-8075,1095-9203
DOI: 10.1126/science.294.5541.269b